You can pray whenever you want with your Alexa. Start by enabling the Episcopal Prayer Skill here. Or by saying “enable Episcopal Prayer skill”. After that say “Alexa, open Episcopal Prayer”. She’ll start with saying “The Lord be with you” and adds a prayer, some assigned readings, the Lord’s Prayer and some more.
Or you can pray the Daily Office with podcasts. In your podcast app, search for A Morning at the Office for morning prayer, An Evening at Prayer for evening prayer, or Daily Prayer from Forward Movement for a general prayer.
You can also listen to the Forward Day by Day podcast instead of reading the devotional.